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  Home >>MSDS>> Content
  Barium Nitrate MSDS
 
Material Safety Data Sheet
BARIUM NITRATE
1. Product Identification & Company
Synonyms: Barium dinitrate; nitric acid, barium salt; nitrobarite
CAS No.: 10022-31-8
Molecular Weight: 261.34
Chemical Formula: Ba(NO3)2
Product Codes:
J.T. Baker: 1018
Mallinckrodt: 3788
Company: BEST INC., LIMITED.
Add.: Rooms 1318-20, 13/F Hollywood Plaza, 610 Nathan Road, Mongkok,
      Kowloon, Hong Kong
Tel: +852-30774337         Fax: +852-30774338
 
2. Composition/Information on Ingredients
 
  Ingredient            CAS No         Percent        Hazardous                                 
  ---------------------------------------   ------------  
 
  Barium Nitrate      10022-31-8       99 - 100%       Yes                                                                   
 
 
3. Hazards Identification
Emergency Overview
--------------------------
DANGER! STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE. MAY BE FATAL IF SWALLOWED. HARMFUL IF INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. AFFECTS MUSCLES (INCLUDING THE HEART), AND CENTRAL NERVOUS SYSTEM.

J.T. Baker SAF-T-DATA(tm) Ratings (Provided here for your convenience)
---------------------------------------------------------------------
Health Rating: 3 - Severe (Life)
Flammability Rating: 0 - None
Reactivity Rating: 3 - Severe (Oxidizer)
Contact Rating: 2 - Moderate
Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES
Storage Color Code: Yellow (Reactive)
---------------------------------------------------------------------

Potential Health Effects
----------------------------------

Inhalation:
Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath. Systemic poisoning may occur with symptoms similar to those of ingestion.
Ingestion:
Toxic! May cause tightness of the muscles of the face and neck, vomiting, diarrhea, abdominal pain, muscular tremors, anxiety, weakness, labored breathing, cardiac irregularity, convulsions, and death from cardiac and respiratory failure. Estimated lethal dose lies between 1 to 15 grams. Death may occur within hours or up to a few days. May cause kidney damage.
Skin Contact:
Causes irritation to skin. Symptoms include redness, itching, and pain.
Eye Contact:
Causes irritation, redness, and pain.
Chronic Exposure:
No information found.
Aggravation of Pre-existing Conditions:
Persons with pre-existing skin and nervous system disorders or impaired respiratory or kidney function may be more susceptible to the effects of this substance.
 
4. First Aid Measures
Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion:
Get medical attention immediately. Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. After vomiting, a mixture of 1 tablespoon of sodium or magnesium sulfate (Epsom salts) dissolved in 8 oz. of water to drink maybe indicated to precipitate the barium as the nontoxic and insoluble barium sulfate.
Skin Contact:
Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention.

Note to Physician:
Monitor patients with significant ingestion for respiratory, cardiovascular, and blood pressure status. Watch for cardiac arrhythmias, respiratory failure due to flaccid paralysis of respiratory muscles, pulmonary edema, vocal cord paralysis, severe hypertension, and late effect kidney failure. Acute barium poisoning results in hypokalemia. The administration of fluids containing dilute concentrations of potassium salts may be indicated.
 
5. Fire Fighting Measures
Fire:
Not combustible, but substance is a strong oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition.
Explosion:
Contact with oxidizable substances may cause extremely violent combustion. See section 10. Sensitive to mechanical impact.
Fire Extinguishing Media:
Use flooding amounts of water in early stages of fire. Foam, dry chemical, or carbon dioxide may also be used. Do not use water on molten material. Emits nitrogen oxides when heated to decomposition.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. Do not release runoff from fire control methods to sewers or waterways.
 
6. Accidental Release Measures
Ventilate area of leak or spill. Keep unnecessary and unprotected people away from area of spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Pick up and place in a suitable container for reclamation or disposal, using a method that does not generate dust.

 
7. Handling and Storage
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Separate from combustibles, organic or other readily oxidizable materials. Avoid storage on wood floors. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.
 
8. Exposure Controls/Personal Protection
Airborne Exposure Limits:
For Soluble Barium Compounds:
OSHA Permissible Exposure Limit (PEL):
0.5 mg (Ba)/m3
ACGIH Threshold Limit Value (TLV):
0.5 mg (Ba)/m3 A4 - not classifiable as a human carcinogen
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
If the exposure limit is exceeded, a full facepiece respirator with dust/mist filter may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection:
Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.
 
9. Physical and Chemical Properties
Appearance:
White crystals.
Odor:
Odorless.
Solubility:
8.7 grams/100 g water @ 20C (68F).
Density:
3.24 @ 23C (73F)
pH:
No information found.
% Volatiles by volume @ 21C (70F):
0
Boiling Point:
Decomposes.
Melting Point:
592C (1098F)
Vapor Density (Air=1):
No information found.
Vapor Pressure (mm Hg):
No information found.
Evaporation Rate (BuAc=1):
No information found.
 
10. Stability and Reactivity
Stability:
Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products:
Oxides of nitrogen and toxic metal fumes may form when heated to decomposition.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Magnesium plus barium oxide plus zinc, aluminum and magnesium alloys, combustibles (paper, oil, wood),acids, and oxidizers. Mixtures with finely divided aluminum-magnesium alloys are easily ignitable and extremely sensitive to friction or impact.
Conditions to Avoid:
Heat, dusting, contact with combustibles and incompatibles.
 
11. Toxicological Information

For Barium Nitrate: Oral rat LD50: 355 mg/kg. Irritation Data: Skin rabbit 500 mg/24H mild. Eye rabbit 100 mg/24H moderate.
  --------\Cancer Lists\------------------------------------------------------
                                         ---NTP Carcinogen---
  Ingredient                             Known    Anticipated    IARC Category
  ------------------------------------   -----    -----------    -------------
  Barium Nitrate (10022-31-8)             No          No            None

12. Ecological Information
Environmental Fate:
This material may bioaccumulate to some extent.
Environmental Toxicity:
No information found.
 
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste facility. Although not a listed RCRA hazardous waste, this material may exhibit one or more characteristics of a hazardous waste and require appropriate analysis to determine specific disposal requirements. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
 
14. Transport Information
Domestic (Land, D.O.T.)
-----------------------
Proper Shipping Name: BARIUM NITRATE
Hazard Class: 5.1, 6.1
UN/NA: UN1446
Packing Group: II
Information reported for product/size: 400LB

International (Water, I.M.O.)
-----------------------------
Proper Shipping Name: BARIUM NITRATE
Hazard Class: 5.1, 6.1
UN/NA: UN1446
Packing Group: II
Information reported for product/size: 400LB
 
15. Regulatory Information
  --------\Chemical Inventory Status - Part 1\-----------------------
  Ingredient                      TSCA       EC   Japan  Australia
  -----------------------------------------------  ----  ---  -----
  Barium Nitrate (10022-31-8)        Yes     Yes    Yes      Yes                                     
 
  --------\Chemical Inventory Status - Part 2\------------------------
                                             --Canada—
  Ingredient                          Korea  DSL   NDSL  Phil.
  -----------------------------------------------  -----  ---   ---- 
  Barium Nitrate (10022-31-8)          Yes   Yes   No     Yes       
 
  --------\Federal, State & International Regulations - Part 1\--------
                                   -SARA 302-    ------SARA 313------
  Ingredient                     RQ    TPQ     List  Chemical Catg.
  -----------------------------------------  ---   -----   ----  --
  Barium Nitrate (10022-31-8)     No    No      No    Barium compo
 
  --------\Federal, State & International Regulations - Part 2\--------
                                     -RCRA-    -TSCA-
  Ingredient                    CERCLA     261.33     8(d)
  -----------------------------------------  ------     ------    -
  Barium Nitrate (10022-31-8)      No         No         No     
 
 Chemical Weapons Convention:  No     TSCA 12(b):  No     CDTA:  No
SARA 311/312:  Acute: Yes      Chronic: Yes  Fire: No  Pressure: No
Reactivity: No          (Pure / Solid)


Australian Hazchem Code: 2W
Poison Schedule: S6
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.
16. Other Information
NFPA Ratings: Health: 3 Flammability: 0 Reactivity: 0 Other: Oxidizer
Label Hazard Warning:
DANGER! STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE. MAY BE FATAL IF SWALLOWED. HARMFUL IF INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. AFFECTS MUSCLES (INCLUDING THE HEART), AND CENTRAL NERVOUS SYSTEM.
Label Precautions:
Keep from contact with clothing and other combustible materials.
Avoid breathing dust.
Avoid contact with eyes, skin and clothing.
Store in a tightly closed container.
Use only with adequate ventilation.
Wash thoroughly after handling.
Label First Aid:
If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. In all cases call a physician.
Product Use:
Laboratory Reagent. 
 
 
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